A third disc, titled "Oddities and Duets," will feature some of Osbourne's "most unusual collaborations," according to a press release, including "For Heaven's Sake" with the Wu-Tang Clan, "Born to Be Wild" with Miss Piggy and "Nowhere to Run (Vapor Trail)" with The Crystal Method, DMX and Ol' Dirty Bastard.

The fourth disc, titled "Under Covers," comprises Osbourne's renditions of some of his favorite works by other artists, such as "In My Life" (The Beatles), "Sympathy for the Devil" (Rolling Stones) and "21st Century Schizoid Man" (King Crimson)." Guitarists Jerry Cantrell (Alice in Chains), Robert Randolph (Robert Randolph & The Family Band) and Leslie West (Mountain) appear on the set.

Ozzy Osbourne's "Prince of Darkness" track list:

Disc 1
1. "I Don't Know" (live)
2. "Mr. Crowley"
3. "Crazy Train"
4. "Goodbye to Romance" (live)
5. "Suicide Solution" (live)
6. "Over the Mountain"
7. "Flying High Again" (live)
8. "You Can't Kill Rock and Roll"
9. "Diary of a Madman"
10. "Bark at the Moon" (live, B-Side)
11. "Spiders" (B-Side)
12. "Rock and Roll Rebel"
13. "You're No Different"

Disc 2
1. "Ultimate Sin" (live)
2. "Never Know Why" (live)
3. "Thank God for the Bomb" (live)
4. "Crazy Babies"
5. "Breakin' All the Rules"
6. "I Don't Want to Change the World" (demo)
7. "Mama, I'm Coming Home" (demo)
8. "Desire" (demo)
9. "No More Tears"
10. "Won't Be Coming Home (S.I.N.)" (demo)
11. "Perry Mason" (live)
12. "See You on the Other Side"*
13. "Walk On Water"*
14. "Gets Me Through" (live)
15. "Bang Bang"*
16. "Dreamer"

* Previously Unreleased

Disc 3
1. "Iron Man" (with Therapy)
2. "N.I.B.." (with Primus)
3. "Purple Haze" (with Zakk Wylde, Randy Castillo, Geezer Butler)
4. "Pictures of Matchstick Men" (with Type O Negative)
5. "Shake Your Head" (Let's Go To Bed) (with Was Not Was)
6. "Born to Be Wild" (with Miss Piggy)
7. "Nowhere to Run" (Vapor Trail) (with Crystal Method, DMX, Ol' Dirty Bastard & Fuzzbuble)
8. "Psycho Man" (Black Sabbath)
9. "For Heaven's Sake 2000" (with Tony Iommi & Wu-Tang Clan)
10. "I Ain't No Nice Guy" (with Motorhead)
11. "Therapy" (with Infectious Grooves)
12. "Dog, The Bounty Hunter" (A&E Series Theme Song)

Disc 4
1. "21st Century Schizoid Man" (originally recorded by King Crimson)
2. "Mississippi Queen" (originally recorded by Mountain)
3. "All The Young Dudes" (originally recorded by Mott the Hoople)
4. "In My Life" (originally recorded by The Beatles)
5. "Fire" (originally recorded by Arthur Brown)
6. "For What It's Worth" (originally recorded by Buffalo Springfield)
7. "Sympathy for the Devil (originally recorded by The Rolling Stones)
8. "Working Class Hero" (originally recorded by John Lennon)
9. "Good Times" (originally recorded by Eric Burdon)
10. "Changes" (with Kelly Osbourne) (originally recorded by Black Sabbath)